Vanadia/titania catalysts for gas phase partial toluene oxidation: Spectroscopic characterisation and transient kinetics study

Abstract

Formation of vanadia species during the calcination of ball milled mixture of V 2O 5 with TiO 2 was studied by Raman spectroscopy in situ and at ambient conditions. It is found that calcination in air leads to fast (1–3 h) spreading of vanadia over TiO 2 followed by a slower process leading to the formation of a monolayer vanadia. The calcinated catalyst showed higher activity during toluene oxidation than the uncalcinated one, but the selectivity towards C 7-oxygenated products (benzaldehyde and benzoic acid) remains unchanged. The activity of the catalysts is ascribed to the formation of vanadia species in the monolayer. The details of the parallel–consecutive reaction scheme of toluene oxidation are presented from steady-state and transient kinetics studies. Different oxygen species seem to participate in the deep and partial oxidation of toluene. Coke formation was observed during the reaction presenting an average composition C 2 n H 1.1 n . The amount of coke on the catalyst was not dependent on the calcination step and the vanadium content in the catalyst. Coke formation was seen to be responsible for the deactivation of the catalyst.