Abstract

Abstract The performance of vanadia-doped titania-pillared clay (V/Ti-PILC) in the selective catalytic oxidation of H 2 S was investigated in this study. A series of V/Ti-PILC with various amounts of vanadia were prepared and characterized. XRD analysis revealed the presence of titania anatase peak without any evidence of crystalline vanadia. V/Ti-PILC showed a very good catalytic performance towards H 2 S oxidation at temperatures ranging from 220–300 °C without the considerable emission of SO 2 . At 300 °C, all the catalysts showed high H 2 S conversion of about 85%. The H 2 S conversions over V/Ti-PILC increased with increasing vanadia content and temperature.

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