Abstract
The main purpose of this paper is to apply the quantum statistical mechanical model for polarizable fluids, used by Høye-Stell and others, to the calculation of the van der Waals force (dispersion force) between monatomics. The results are in agreement with those obtained by quantum perturbation theory. The quantum statistical method implies considerable formal simplifications. The introductory sections of the paper show, for illustrative purposes, how the dispersion forces in limiting cases also can be obtained from macroscopic quantum electromagnetic theory when two dilute dielectric media with plane-parallel surfaces are separated by a vacuum (Casimir effect).
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More From: Physica A: Statistical Mechanics and its Applications
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