Abstract

Industrial chemicals differ in their treatment methods and types, depending on their physicochemical properties. Highly volatile chemicals are emitted despite installation of preventive facilities, such as scrubbers and adsorption towers. Some countries release a Toxic Release Inventory (TRI), which is a mandatory report on the amount of chemicals emitted annually. This report is released to the citizens to ensure their right to knowledge and life. Numerous methods have been devised to investigate the amount of chemical emissions. There are four methods to estimate TRI emissions (Emission Factor Method; Material Balance Method; Source Testing Method; Emission Model Method). Moreover, efforts have been made to increase awareness and formulate plans to reduce chemical emissions. Despite this, the TRI method tends to underestimate and overestimate, especially due to volatile compounds. If the results of the TRI emissions are underestimated, toxic chemicals can have a negative impact on citizens. Volatile compounds are commonly used in chemical manufacturing plants, such as paint plants. In this study, a suitable method for each industrial process was suggested based on conservative estimates of multiple toxic chemical inventory method, focusing on the paint manufacturing process. In the paint manufacturing plant, storage, weighing, and mixing processes should be used emission model method to estimate TRI. In the reaction process, TRI must be estimated by the source test method. In the transfer process, the emission factor method should be used to estimate TRI. In the atmosphere prevention process, the emission factor method or source testing method should be used depending on the physical and chemical properties such as vapor pressure of the chemical.

Highlights

  • Accidents that occur at chemical plants affect not just the surrounding environment and humans

  • The emission factor method of the air pollution prevention facility is calculated assuming that the Toxic Release Inventory (TRI) emissions generated by the emission model method of each process are transferred to the adsorption tower

  • The purpose of this study is to evaluate the applicability of the TRI emission estimation method

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Summary

Introduction

Accidents that occur at chemical plants affect not just the surrounding environment (air, water, soil, etc.) and humans. Many chemical accidents have occurred worldwide, leading to the creation of various safety management systems. In 1976, an accident occurred in Seveso, Italy, where chlorine gas and dioxin leaked into the atmosphere, causing damage to 11 nearby villages. This led to the enactment of the Seveso Directive. States introduced the Process Safety Management regulations, which strengthened internal chemical safety management [1]. The MIC (Methyl Isocyanate) explosion in 1984 in Bhopal, India, and the 1984 explosion in the West Virginia chemical plant in the United States revealed the need for stringent and

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