Abstract
Pyrolytic lignin is the collective name of the lignin-derived fraction of pyrolysis liquids. Conversion of this fraction to biobased chemicals is considered an attractive valorization route. Here we report experimental studies on the ozonation of a pine-derived pyrolytic lignin dissolved in methanol (33 wt %). Results show a high reactivity of ozone, and a molecular weight reduction of up to 40% was obtained under mild conditions (0 °C, atmospheric pressure) without the need for catalysts. Detailed analysis of the product mixtures (GC/MS-FID, HPLC, GPC, NMR) showed the presence of low molecular weight (di)acids and esters, along with larger highly oxygenated aliphatics. A reaction network is proposed including the heterolytic cleavage of aromatic rings, followed by secondary reactions. The observations were supported by experimental studies using representative pyrolytic lignin model compounds and a biosynthetic lignin oligomer, which aided further elucidation on the reactivity trends for different chemic...
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
