Valorization of calcium hypochlorite precipitate as a new source of heterogeneous catalyst development for biodiesel production: A preliminary experiment

Abstract

One of the main problem related with liquid bleach production from calcium hypochlorite is the amount of precipitates generated and its consequent management. As a result, academic and industrial communities have been challenged with searching of a means for its valorization. Therefore, this research explores the application of the precipitate as a viable source of Ca-based heterogeneous catalyst development for the production of waste cooking oil methyl esters for the first-time. The catalyst was prepared by dividing the precipitates into three forms, viz. raw untreated (RC), heat treated (RC-TB), and NaOH impregnated plus thermally activated (RC-ITB). The prepared catalysts were efficiently characterized by XRF, XRD, FTIR, SEM, and BET techniques. The characterization results indicated that the catalysts are mainly composed of calcium metal in the form of oxides (CaO), calcite (CaCO3) and Portlandite (Ca(OH)2), which are the promising constituents of basic catalysts. The BET inspection of RC, RC-TB, and RC-ITB revealed the specific surface area of 8.509, 9.089, and 9.312 m2/g, respectively. At the same reaction conditions, the maximum biodiesel yield of 76.05 % was achieved by RC-ITB compared to RC-TB (62.57 %) and RC (19.74 %), because it's larger specific surface area and highest basic nature (pH = 12.65 at 1:5 w/v) improves the reaction catalysis through better catalyst-substrates interactions. The lower biodiesel yield was attained through the RC catalyst due to its untreated surface, lower specific area, and weak alkaline nature (pH value = 10.66 at 1:5 w/v). Furthermore, regardless of the amount of yield, almost similar fuel properties and functional groups of the products over the coded catalysts were observed. Generally, the possibility of calcium hypochlorite precipitate as a precursor of Ca-based heterogeneous catalyst has been effectively proven in this research, which could be very important for environmental safety and industrial resource integration.