Validation of Version 1.3 Ozone Measured by the SOFIE Instrument

Abstract

AbstractThe Solar Occultation for Ice Experiment (SOFIE) has operated aboard the Aeronomy of Ice in the Mesosphere (AIM) satellite since 2007. SOFIE uses solar occultation to retrieve ozone (O3) profiles from ∼20 to 100 km altitude, typically at polar latitudes. This study validates SOFIE O3 profiles, including error analysis and comparisons with independent observations. Comparisons are made to the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE‐FTS) and the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) satellite instruments. SOFIE shows qualitative and quantitative agreement with both data sets between 30 and 70 km and better overall agreement in the northern hemisphere. SOFIE and ACE mean differences are typically within 20% in the 30–70 km altitude range. SOFIE and MIPAS exhibit mean difference values within 30% in the winter and 20% for all other seasons averaged, between ∼30 and 60 km. Seasonal comparisons indicate similar variations in both hemispheres and through all seasons. The comparisons indicate that SOFIE is biased 5%–10% low at 30–70 km altitudes, with greater differences at higher and lower altitudes. The comparisons are challenging due to the low O3 concentrations at high altitudes, the limited number of coincidences, and the large diurnal variation in mesospheric O3 during twilight hours.