Abstract
EuLγ4 emission spectra show a large chemical shift (∼5 eV), depending on the valence state of a compound. The applicability of this emission to valence-selective X-ray absorption fine structure spectroscopy was demonstrated by performing partial fluorescence yield measurements using a 1:1 mixture of EuS and Eu2O3 and using valence-fluctuating compounds, such as Eu3Pd20Ge6 and BaMgAl10O17:Eu.
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