Abstract

The development of the fine structure of the np 5 ( n + 1 ) s and np 5 ( n + 1 ) p ( n = 2 in Na, n = 3 in K, n = 4 in Rb, n = 5 in Cs) configurations of alkali atoms ions from LS-coupling to jK-coupling has been studied by comparing the experimental photoelectron spectra with the results obtained with analytical LS-coupling and jK-coupling models.

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