Abstract

Measurements of the magnetic susceptibility, electrical resistivity, and heat capacity are reported for the polycrystalline YbNiAl4 intermetallic compound. χ(T) has been measured up to 1000 K and its behavior is typical of a compound with the valence fluctuation between Yb3+ and Yb2+. This is especially evident from a broad maximum observed at 400 K and interpreted in frames of the interconfiguration fluctuation model. The Sommerfeld coefficient derived from the heat capacity measurements takes a small value of γ=16 mJ mol−1 K−2. The low temperature resistivity follows the AT2 dependence characteristic of a Fermi liquid.

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