Abstract
The valence-band structure of single crystals of titanium carbide (TiC) and titanium nitride (TiN) have been studied with angle-integrated photoelectron spectroscopy using ${\mathrm{He}}_{\mathrm{I}}$, ${\mathrm{He}}_{\mathrm{II}}$, and synchrotron radiation for excitation. The results are compared with the partial densities of states derived from an augmented-plane-wave band-structure calculation. Peak positions and widths agree fairly well, but the observed intensity modulations with photon energy cannot be interpreted by such a comparison.
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