Abstract
The new compound (NEt4)[(acac)2RuS2ReS2Ru(acac)2] was characterized by cyclic voltammetry to reveal reversible reduction and oxidation behavior. While the redox products proved EPR silent, the UV–Vis-NIR spectroelectrochemistry showed shifted charge-transfer absorptions and a typical near-infrared intervalence (RuII→RuIII) band at λmax=1725nm (ε=1800M−1cm−1) for the one-electron oxidized intermediate. The results are discussed in comparison to those obtained for [(bpy)2RuS2ReS2Ru(bpy)2]Cl3.
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