Abstract

SbBr 3 molecules in the gas phase were dissociated by 193 and 248 nm laser radiation. The fluorescence was dispersed by a monochromator. Highly excited atomic levels of Sb were found to be significantly populated for three- or four-photon dissociation. A region of continuous fluorescence in the visible range around 550 nm was attributed to the diatomic SbBr radical resulting from a two-photon dissociation. Only weak lines of atomic bromine, but from high levels, were found. A broad weak continuous fluorescence in the UV remains unassigned.

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