Abstract
The ultraviolet (UV) absorption spectra were measured for amorphous and crystalline H2O/HNO3 films representative of polar stratospheric clouds (PSCs). Film compositions were determined using laser induced thermal desorption (LITD). Pure HNO3 films showed a broad absorption peak with a maximum absorbance at λ ≈ 195 nm. The absorbances of amorphous H2O/HNO3 films were also broad and peaked at λ=196–198 nm. The absorption cross sections increased slightly for more dilute films, although the band shape was nearly independent of the H2O content This increase in cross section was consistent with a change in the absorbing species from molecular HNO3 to ionic NO3−. The major absorbing species in crystalline NAT, NAD, and NAM is also NO3− and these films all had very similar UV absorption spectra. Their absorption peaks were all at λ ≈ 200 nm and the band shapes were nearly identical.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
