Utilizing bis(imino)dihydroacridanide pincer ligands in p-block chemistry: synthesis and catalysis of an antimony monocation salt.

Abstract

We present the synthesis and characterization of an Sb(III) monocation salt stabilized by a bulky bis(imino)dihydroacridanide pincer ligand. The Lewis acidity of the Sb cation is quantified using the Guttmann-Beckett method and confirmed by its reaction with 4-dimethylaminopyridine, which forms a Lewis acid-base adduct. This Sb cation exhibits catalytic activity in the cyanosilylation of arylketones. The electronic structure of the Sb cation as well as the mechanism of the catalytic transformation are explored by density functional theory computations.