Utilization of standards generated in the process of thermal decomposition chemically modified silica gel for a single point calibration of a GC/FID system

Abstract

The utilization of a multicomponent gaseous standard mixture, containing CO and CO 2 and obtained by thermal decomposition of a so-called immobilized compound, for a single point calibration of a GC/FID system are described. The generation of such a mixture takes place as a result of thermal decomposition of a sample of chemically modified silica gel placed in a heated chamber of thermal desorber coupled with the device being calibrated via a catalytic methanizer. The mean amount of the analyte librated from unit mass of the gel was 0.71 mg g −1 (RSD = 3%) for carbon monoxide and 0.86 mg g −1 (RSD = 3%) for carbon dioxide.