Utilization of rice husk and waste aluminum cans for the synthesis of some nanosized zeolite, zeolite/zeolite, and geopolymer/zeolite products for the efficient removal of Co(II), Cu(II), and Zn(II) ions from aqueous media

Abstract

In this paper, rice husk and waste aluminum cans were exploited as silicon and aluminum sources, respectively for the low-cost synthesis of some nanosized zeolite, zeolite/zeolite, and geopolymer/zeolite products. XRD confirmed that the synthesized geopolymer/zeolite products are geopolymer/zeolite A (has a crystallite size of 58.44 nm & abbreviated as G1) and geopolymer/faujasite (has a crystallite size of 25.58 and 20.26 nm & abbreviated as G2 and G3, respectively). Also, the synthesized zeolite products are sodium aluminum silicate hydrate (has a crystallite size of 27.65 and 41.85 nm & abbreviated as H1 and H2, respectively). Besides, the synthesized zeolite/zeolite product is sodium aluminum silicate hydrate/zeolite A (has a crystallite size of 66.01 nm and abbreviated as H3). Moreover, the synthesized products were characterized using other tools such as HR-TEM, FE-SEM, EDX, and FT-IR. The synthesized products were efficiently applied for removing Co(II), Cu(II), and Zn(II) ions from aqueous media and wastewater which was taken from Abuzaabal- Qalyubiyah-Egypt. The maximum uptake capacity of G3 sample toward Co(II), Cu(II), and Zn(II) ions is 134.24 ± 1.26, 126.26 ± 0.32, and 131.93 ± 0.87 mg/g, respectively. The uptake of the studied metal ions is spontaneous, chemical, exothermic, and fitted well with the Langmuir isotherm and pseudo-2nd-order kinetic model.