Utilization of olive pomace in nano MgO modification for sorption of Ni(II) and Cu(II) metal ions from aqueous solutions

Abstract

Magnesium oxide nanoparticles were synthesized and modified by olive pomace (NMOOP700) as a novel sorbent and characterized using Fourier Transform Infrared Spectra, Scanning Electron Microscope, Transmission Electron Microscope, X-ray Diffraction, Differential Thermal Analysis and Thermal Gravimetric Analysis. Sorption of Cu (II) or Ni (II) ions were achieved taking into account important parameters including initial pH of the medium, contact time, initial metal ion concentration and temperature. A comparative study between Magnesium oxide nanoparticles and NMOOP700 material for the sorption of Cu (II) or Ni (II) ions was implemented. The obtained data revealed that the sorption process is significantly improved using NMOOP700. The monolayer capacity of Ni (II) and Cu (II) metal ions on NMOOP700 at pH 5 were found to be 149.93 ± 4.4 and 186.219 ± 6.3 mg/g, respectively. Findings of the present work highlight the potential use of NMOOP700 as a novel and effective sorbent material for the removal of Cu (II) or Ni (II) ions from the liquid phase.