Abstract
A new method, proposed by authors, of utilization of chloroorganic waste accompanying the production of 1,2-dichlorethane consists in alkaline dehydrochlorination of this waste (equations 1-5) and simultaneous copolymerization with the unsaturated hydrocarbons of C 5 -C 9 fraction. At the first stage of the process at ambient temperatures (≤ 50 °C) ionic polymerization and copolymerization of the non-saturated components, take place. Then, at higher temperatures (> 50 °C) the free radical homopolymerization and copolymerization of vinyl chloride and vinylidene chloride most probably proceed. As a final product, oligomeric and polymeric resin-like products are formed, which can be recommended for the use as hydroisolating material.
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