Utilization of air granulated basic oxygen furnace slag as a binder in belite calcium sulfoaluminate cement: A sustainable alternative

Abstract

Basic oxygen furnace (BOF) slag negatively impacts ordinary Portland cement performance when replacement levels exceed 5%. This necessitates the exploration of alternative applications for the slag. Simultaneously, a high-volume slag utilization is desired to benefit slag recycling as supplementary cementitious materials. Therefore, this study aims to optimize the air granulated BOF slag substitution potential in belite calcium sulfoaluminate cement by investigating the hydration products in standard mortar. The reactivity of the novel binder is correlated with workability, and mechanical performance by thermal, mineralogical, and microstructure analysis. Consequently, the 10–30% replacement delays the final setting time by inhibiting the ettringite formation leading to a decrease in mechanical performance till 28 days. At later ages (28–180 days), the 30–50% substitution exhibited the synergy in mechanical performance, which is attributed to the hydrogarnet, calcium silicate hydrate, and strätlingite formation. Moreover, all the mortar samples exhibited heavy metals’ leaching and drying shrinkage below the permissible limit.