Abstract
The external penetration of ions into cementitious materials plays an important role in long-term durability of concrete structures. Current test methods to study bulk diffusion of ions in cement-based materials are typically destructive, time consuming and labor intensive. This research work uses laboratory transmission X-ray microscopy (TXM) and X-ray computed microtomography (μCT) to image iodide diffusion in cement paste. These techniques can non-destructively image the distribution of the dissolved ions at 8.8μm resolution in minutes with a 2D analysis and a few hours for 3D. This method does not aim to measure the size of the pores, instead it aims to image the movement of the fluid through the pores by imaging an electron dense tracer with similar behavior as chloride ions. The tests were completed on cement paste mixtures with water-to-cement ratios (w/c) of 0.35, 0.40, and 0.45. The findings were validated with micro X-ray fluorescence (μXRF) imaging. Iodide and chloride diffusivity is also compared for paste samples with w/c of 0.40 and shown to provide comparable results. Results are also presented of 3D ion diffusion and void filling at high degrees of saturation.
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