Using Waste Tire-Derived Particles to Remove Benzene and n-Hexane by Dynamic and Static Adsorption.

Abstract

Scrap tire rubber particles were used and evaluated to adsorb some gaseous volatile organic compounds (VOCs), such as benzene and n-hexane. The results present that the adsorption capacities were 0.18 and 0.072 mg/g for n-hexane and benzene, respectively, in the static adsorption mode; the effective adsorption may be attributed to the carbon black of the tire. The adsorption process is in accordance with the Freundlich isothermal model and Lagergren pseudo-first-order kinetic equation. Correspondingly, the adsorption process is multilayer adsorption analyzed by the intramolecular diffusion model. In the dynamic adsorption mode, the maximum adsorption efficiencies of n-hexane and benzene were 80.7 and 81%, respectively, at flow velocities of 0.1 L/min n-hexane and 0.2 L/min benzene.