Using Volatile Organic Compounds in Waste Streams as Fuel

Abstract

Abstract To meet the environmental regulations, volatile organic compounds (VOC) in waste streams of various industries are thermally oxidized before being released to the atmosphere. This thermal oxidation process requires use of additional fuel and energy, has high operational costs and requires frequent maintenance. As an alternative, these VOCs can be considered as fuels themselves. Even without considering the energy used for the supplemental fuel such as natural gas, the enthalpy of the VOCs incinerated is not negligible. Hydrogen, a valuable energy carrier, can be produced from VOCs by reforming them. In this study, a system that can reform VOCs in the exhaust stream of paint finishing operations and use it to produce hydrogen that can be used in a fuel cell for power generation was designed. Steam reforming experiments were conducted on different VOCs using a 10 % Co/CeO2 catalyst. The effect of different functional groups and the chain length was examined. This study shows the potential of dilute VOCs in the waste stream of many industries if they can be recovered and used as a fuel effectively instead of being incinerated.