Abstract

Gambling is a useful analog to thermodynamics. When all players use the same dice, loaded or not, on the average no one wins. In thermodynamic terms, when the system is homogeneous—an assumption made by Boltzmann in his H-Theorem—entropy never decreases. To reliably win, one must cheat, for example, use a loaded dice when everyone else uses a fair dice; in thermodynamics, one must use a heterogeneous statistical strategy. This can be implemented by combining within a single system, different statistics such as Maxwell-Boltzmann’s, Fermi-Dirac’s and Bose-Einstein’s. Heterogeneous statistical systems fall outside of Boltzmann’s assumption and therefore can bypass the second law. The Maxwell-Boltzmann statistics, the equivalent of an unbiased fair dice, requires a gas column to be isothermal. The Fermi-Dirac and Bose-Einstein statistics, the equivalent of a loaded biased dice, can generate spontaneous temperature gradients when a field is present. For example, a thermoelectric junction can produce a spontaneous temperature gradient, an experimentally documented phenomenon. A magnetic field parallel to, and an electric field perpendicular to a surface produce a spontaneous current along the surface, perpendicular to both fields (Reciprocal Hall Effect). Experimental data collected by several independent researchers is cited to support the theory.

Highlights

  • In thermodynamic terms, when the system is homogeneous—an assumption made by Boltzmann in his H-Theorem—entropy never decreases

  • Variants of the H-Theorems for quantum systems have been developed by several researchers such as Von Neumann and Tolman [6] [7] [8], but, just like Boltzmann, they assume statistical homogeneity which, from the outset, precludes cheating

  • As per Equation (6), T is invariant with elevation, the column is isothermal as could have been predicted by Clausius version of the second law

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Summary

Introduction

Fermions are known to comply with the Fermi-Dirac distribution and bosons with the Bose-Einstein distribution These quantum statistics are the equivalent of loaded dice as they generate biased outcomes compared to the classical Maxwell-Boltzmann distribution and with each other. Variants of the H-Theorems for quantum systems have been developed by several researchers such as Von Neumann and Tolman [6] [7] [8], but, just like Boltzmann, they assume statistical homogeneity which, from the outset, precludes cheating This assumption is not always true in Vegas despite being a casino rule-and overly restrictive in the physical world, Boltzmann notwithstanding. 3) Multiple non-maxwellian gases heterogeneously distributed in space and with different statistics can produce temperature gradients These gradients can be used to generate energy, thereby bypassing the second law

Homogeneous Maxwellian Statistics-One Fair Dice Shared by Everyone
Homogeneous Quantum Statistics—One Loaded Dice Shared by Everyone
Heterogeneous Quantum Statistics
Biased Half-Maxwellian Statistics
Experimental Data
Epicatalysis
Conclusions
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