Abstract
The relaxation behavior of vitrimers that is dominated by chemical exchange reactions plays a critical role in vitrimer processing and applications such as self-healing, welding, and others involving the dynamic nature of the vitrimers. Here, we use atomic force microscopy to image embedding of gold nanospheres into epoxy-based vitrimers to assess the surface and bulk relaxation in this material. The results show that even at temperatures well below the bulk topology freezing transition temperature, the nanospheres embed into the vitrimers. The activation energy for the relaxation at the surface and in bulk were estimated in the single measurement, and the former is found to be much lower than the latter. The increase in the surface relaxation is attributed to a combination of an acceleration effect on relaxation by network defects and a decrease in the number of intermolecular exchanges at the surface.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Langmuir : the ACS journal of surfaces and colloids
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
