Abstract
AbstractFour cyclam‐based fluorescent molecular probes were prepared using “click” chemistry and investigated to determine the effect of the triazole connectivity and fluorophore substitution on the photophysical properties and metal‐ion response mechanism. The fluorescence of the ligands is turned on in the presence of ZnII but varies in intensity depending on the solvent; the highest signal changes are found in MeCN. Complexation with CuII leads to fluorescence quenching, but only in the aqueous solvent, in which the triazole is involved in coordination of the metal. The length of the pendant triazole arm influences the ligand field around pentacoordinate CuII to yield a distorted square‐planar coordination geometry in the ligands with an ethylene linker. The quantum yield (QY) of the emission intensity can be tuned by the triazole substitution, thereby resulting in increases in QY of more than one order of magnitude (ligand 1 versus 3). Changing the fluorophore opens up alternative radiative processes, thus leading to phosphorescence‐like behavior in coumarin probe 2. Steady‐state fluorescence emission spectra of the free ligands and their respective CuII complexes in a “glass environment” reveal two different inherent fluorescence quenching mechanisms. In the free ligands an electron‐transfer deactivates the excited chromophore, whereas in the CuII complexes it is energy transfer that results in complete quenching of the emission of the ligands.
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