Use of response surface methodology for optimization of fluoride adsorption in an aqueous solution by Brushite

Abstract

In the present study, Response surface methodology (RSM) was employed for the removal of fluoride on Brushite and the process parameters were optimized. Four important process parameters including initial fluoride concentration (40–50mg/L), pH (4–11), temperature (10–40°C) and B dose (0.05–0.15g) were optimized to obtain the best response of fluoride removal using the statistical Box–Behnken design. The experimental data obtained were analyzed by analysis of variance (ANOVA) and fitted to a second-order polynomial equation using multiple regression analysis. Numerical optimization applying desirability function was used to identify the optimum conditions for maximum removal of fluoride. The optimum conditions were found to be initial concentration=49.06mg/L, initial solution pH=5.36, adsorbent dose=0.15g and temperature=31.96°C. A confirmatory experiment was performed to evaluate the accuracy of the optimization procedure and maximum fluoride removal of 88.78% was achieved under the optimized conditions. Several error analysis equations were used to measure the goodness-of-fit. Kinetic studies showed that the adsorption followed a pseudo-second order reaction. The equilibrium data were analyzed using Langmuir, Freundlich, and Sips isotherm models at different temperatures. The Langmuir model was found to be describing the data. The adsorption capacity from the Langmuir isotherm (QL) was found to be 29.212, 35.952 and 36.260mg/g at 298, 303, and 313K respectively.