Use of positron emission particle tracking to assess mixing of a graphite-based lithium-ion anode slurry in an Eirich mixer

Abstract

The mixing of electrode slurries is a key processing step during the manufacturing of lithium-ion batteries, and poor mixing can have a profound effect on final cell electrochemical performance. This is complicated by the evolving non-Newtonian rheology of these slurries. In this study, Positron Emission Particle Tracking (PEPT) is used to determine the fluid dynamics and dispersion of a model graphite-based anode slurry in an Eirich EL1 mixer, equipped with a rotating pan, wall scraper and internal rotor. The main processes studied are the wetting of graphite particles and breakup of large graphite agglomerates. For experiments performed at different internal rotor tip speeds, with fixed outer pan speed, the dispersion dynamics change with the lowest rotor speed (2 m/s) leaving a large channel of poor mixing between the rotor region and the rotating pan, whilst the mixing within the vessel is mainly driven by the rotating pan. At higher mixing speeds (6 and 10 m/s) more of the vessel volume is active and there is no longer a poor mixing region observed, with 10 m/s tip speed producing the highest intensity of dispersion. An increasing mixer effectiveness (average dispersion across the mixing vessel) as well as an increasing dispersion co-efficient (rate of mixing) is also observed, which will be use to inform scale-up criteria.