Use of open-path FTIR and inverse dispersion technique to quantify gaseous nitrogen loss from an intensive vegetable production site

Abstract

An open-path Fourier transform infrared (OP-FTIR) spectroscopic technique in combination with a backward Lagrangian stochastic (bLS) dispersion model (WindTrax) can be used to simultaneously measure gaseous emissions of N2O, NH3, CH4 and CO2. We assessed the capability of this technique for measuring NH3 and N2O emissions following the application of calcium nitrate (Ca(NO3)2), Nitrophoska (NPK) and chicken manure on a celery farm at Boneo, Victoria, during April and May 2013. We found that the OP-FTIR/WindTrax method was able to measure the diurnal variation in NH3 flux from the field site following application of chicken manure with measured emissions ranging from approximately 0.1–9.8 kg NH3–N ha−1 day−1. The OP-FTIR/WindTrax method also detected a diurnal variation in N2O flux of 1.5–6.2 kg N2O–N ha−1 day−1 and N2O flux increased in response to application of the Ca(NO3)2. We concluded that the OP-FTIR/WindTrax technique can quantify gaseous N loss from vegetable production systems.