Use of Ionic Liquid as Crystallization Inhibitor in Water-Lithium Bromide Absorption Chiller

Abstract

Chillers are used in commercial buildings and industrial plants to provide air conditioning, refrigeration, and process fluid cooling. There are two basic types of chiller cycles: vapor compression and sorption. Sorption chillers are available as either absorption or adsorption designs, depending on the state of the sorbent. Absorption chillers use fluid refrigerants and absorbents (liquid or dissolved), while adsorption chillers employ a solid sorbent (typically silica gel) in combination with a fluid refrigerant. Among the former category, the use of highly hygroscopic LiBr salt as absorbent in combination with H2O as refrigerant comprises LiBr-H2O absorption chillers. Such chillers possess cooling capacities ranging from a few kilowatts (kW) to megawatts (MW) which match with small residential to large scale commercial or even industrial cooling needs. One of the major debilitating factors associated with LiBr-H2O absorption chillers is crystallization. A crystallization event causes a loss of cooling and requires de-crystallization by applying external heat, which results in extensive down-time and requires redundancy designed into a chiller plant. We investigated the use of the imidazolium-based ionic liquid, 1-butyl-3-methylimidazolium bromide ([BMIm]-Br), as crystallization inhibitor additive to LiBr-H2O in the ratio 1:19 [BMIm]-Br:LiBr. It was found that under the operating boundary conditions of 27°C/9°C (cooling water inlet temperature/chilled water outlet temperature), the LiBr-H2O absorption chiller can be operated without modifications and with around 10 K higher heating water inlet temperatures when adding [BMIM]-Br before crystallization occurs compared to pure LiBr-H2O solution. When using the [BMIM]-Br ionic liquid, the refrigeration capacity of the absorption chiller under the above operating conditions and at 85°C heating water inlet temperature exhibited 10% increase after optimizing the solution flow, that lead to higher outputs, such as lower cooling water temperatures. By adding the [BMIM]-Br to the aqueous lithium bromide solution the operating range of the absorption refrigeration system could also be extended to resorption mode, which allows refrigeration below 0 °C. Thus, there is an excellent potential for a significant extension of the application range of LiBr-H2O chillers, e.g. in the field of food cooling and refrigeration processes. Figure 1