Use of a portable infra-red analyzer for low-level hydrocarbon emissions

Abstract

During some on-site tests, a portable infra-red (IR) analyzer was used successfully to monitor for hydrocarbon vapors. The detection limit of the IR analyzer is much lower than that of most other hydrocarbon vapor monitors and can be used in situations where, as in most ambient air monitoring situations, the levels are often less than a milligram per cubic metre (mg/m 3). Traditional procedures used to measure hydrocarbon concentrations at lower levels involves the collection of samples on-site, which are then transported to a laboratory for analysis. The advantage of providing continuous sampling data is that it may indicate trends in the hydrocarbon vapor emissions that may not be apparent using a grab-type sample. The initial tests were designed to determine if the IR analyzer was capable of monitoring the low-level hydrocarbons in a field situation. The findings from that initial work was followed by modification of the test procedure to include an upwind IR analyzer, shortened sampling cycles to produce more data, and additional canister samples collected outside the burn period. The metered grab samples, using Summa canisters, were collected over a 1 h period and any results would therefore, reflect an average value over the hour. The IR analyzer, with a sampling cycle of approximately 1 min, was able to produce a near real-time distribution of the hydrocarbon vapors in the test site emissions. Because the testing parameters and methods are quite different, it is difficult to compare these two methods, but indications suggest strongly that the use of this portable IR instrument could help to describe the hydrocarbon emissions downwind from a source, as well as to monitor for these hydrocarbons continuously, including situations where the levels are below detection limits of most portable detectors.