Abstract
The synthesis and structure of palladium(II) complexes bearing uridato/pyridyl ligands as an anionic N-donor coordination sites are reported. The complexes have been shown to be highly active catalysts for the Heck reaction of aryl bromides (TON 4.0×10 4–9.1×10 4) and moderate activity for the activation of aryl chlorides under phosphine-free conditions.
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