Abstract
The interaction of uranyl compounds with different α-dioximes has been studied. Uranyl complexes with glyoxime, methylglyoxime, dimethylglyoxime, and 1,2-cyclohexanedionedioxime have been synthesized. The X-ray diffraction study of single crystals of [UO2(C3H5N2O2)2{(NH2)2CO}2], [UO2(C6H9N2O2)2(H2O)2] · H2O, [UO2(C6H9N2O2)2(H2O)2] · 6H2O, and [UO2(C6H9N2O2)2(H2O)2]2(CH3CONH2)2 · 6H2O showed a bidentate cyclic coordination of α-dioximes to the central atom through only one oxime group
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