Uranium and metal concentrations in community water systems across the United States, 2006-2011

Abstract

BACKGROUND AND AIM: The US Environmental Protection Agency (EPA) sets maximum contaminant levels (MCLs) for 9 metals/metalloids in public drinking water systems. Beyond arsenic, no nationwide exposure estimates for public drinking water currently exist for these contaminants. Our objective was to estimate exposure to metals in community water systems (CWSs) across the US, to determine if sociodemographic or regional inequalities in these exposures exist, and to identify patterns of exposure for these metals as a mixture. METHODS: We evaluated routine compliance monitoring records for antimony, barium, beryllium, cadmium, chromium, mercury, selenium, thallium, and uranium collected from 2006-2011 (2000-2011 for uranium) by the US EPA in support of the Third Six Year Review for 37,915 CWSs. We focused our analysis on barium, chromium, selenium, and uranium (as arsenic has been reported previously and other metals were mostly undetected), comparing the mean contaminant concentration and the percent of CWSs with MCL excedances across subgroups (US region, sociodemographic county-cluster, size of population served, source water type, and correctional facilities). We evaluated patterns in metal exposure profiles via hierarchical cluster analysis, which also included published CWS arsenic estimates. RESULTS:The percentage of CWSs exceeding the MCL was highest for uranium (3.1% MCL of 30 µg/L, nationwide mean 4.37 µg/L), but lower than previously reported arsenic (2.6%). 75th, 95th percentiles for uranium, chromium, barium, and selenium concentrations were highest for CWSs serving {Semi-Urban, Hispanic} communities, small CWSs, CWSs reliant on groundwater, and those located in the Southwest, similar to previous CWS arsenic findings. Hierarchical cluster analysis revealed four clusters, including an arsenic-uranium-selenium cluster. CONCLUSIONS:{Semi-Urban, Hispanic} communities experience higher average concentrations of metal contaminants, including uranium and arsenic, in public drinking water. Uranium is an under-recognized contaminant in CWSs. Cluster analyses revealed that arsenic and uranium may co-occur in groundwater sources serving CWSs. KEYWORDS: exposure, environmental justice, environmental disparities, water quality