Abstract
As part of our research on the feasibility of producing commodities from lunar regolith by thermal-driven processes with minimal terrestrial precursors we need to characterize, reproduce, and understand thermophysical properties of the molten regolith still unforeseen under the lunar vacuum conditions at a scalable sample size. Two unanticipated phenomena, apparently caused by lunar melt’s surface tension under vacuum, have been revealed in our research work, vacuum void formation and upwards migration. In this paper we present our findings and thinkable explanation on the upwards migration phenomenon experimentally observed and consistently replicated as JSC-1A lunar regolith simulant melted at high vacuum. Upwards migration of molten lunar regolith will make future lunar ISRU’s melting processes both challenging as molten bulk material would migrate upwards along the container’s walls, and also promising on new opportunities for alternative ISRU’s sustainable processes as regolith’s upwards migration takes place in uniformed thin-film pattern. Among the potential ISRU’s processes that might use controlled thermal thin-film-based migration without the necessity of terrestrial precursors are production of feedstock for 3D printing, fractional separation of regolith’s component’s (O2, metals, and alloys) via pyrolysis, film coating, purification of valuables solid crystals including silicon, and fabrication of key elements for microfluidic, and MEMS devices. Thermal upwards migration phenomenon on JSC-1A’s melt is formulated and explained by the authors as due to thermal Marangoni effect (also known as thermo-capillarity) in which temperature gradients within the melt’s bulk and along the crucible’s wall yield the surface tension large enough to supersede the gravitational force and yield the experimentally observed upwards thin-film migration. As far as the authors know, upwards thermal migration of molten JSC-1A (or other lunar simulant regolith) under vacuum has not been reported in the literature. A thermal mathematical model accounting for thermal Marangoni effect on molten JSC-1A agrees with what experimentally was observed, the formation of the meniscus on the melt-wall surface interface along with an incipient upwards migration in thin-film pattern along the crucible wall that, according to the model, experiences large temperature gradient, an important factor to trigger the thermal Marangoni effect along with the fact that surface tension of the molten lunar regolith material is temperature dependent.
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