Abstract
The uptake of chloride and ISA by cement in the degradation stage I was investigated with a combination of sorption experiments and MD simulations. The retention of 36Cl decreases with increasing [Cl−]tot in cement pore water. The uptake of 36Cl is dominated by sorption phenomena and the formation of the Friedel's salt at low and high [Cl−]tot, respectively. ISA sorbs moderately on HCP, and a one-site Langmuir isotherm was used to satisfactorily model the sorption data. MD simulations highlight the key role of Ca in the binding of ISA to C-S-H. This work provides a sound basis for predicting the uptake of chloride and ISA by HCP in the context of L/ILW repositories, together with new insights for the mechanistic understanding of ISA uptake.
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