Upgrading triethanolamine esterquat performance to new levels

Abstract

AbstractTriethanolamine (TEA)‐based esterquat has been the primary ingredient in European fabric softeners for several years and is becoming the global molecule of choice. Although it has an excellent environmental profile, TEA esterquat has been plagued by mediocre performance compared to historical molecules such as dihydrogenated tallow dimethyl ammonium chloride and ditallow imidazoline quat. In this study, the chain lengths, the level of unsaturation, and the source of the raw material (tallow or palm stearine) were varied to better understand their effect on softening and dispersion viscosity. Palm stearine derivatives generally soften as well as tallow derivatives despite the lower C18 content of palm. Various additives were examined to improve dispersibility and other properties such as dye transfer inhibition (DTI) and ease of ironing. DTI is normally accomplished in the wash cycle by additives to the laundry detergent such as polyvinylpyrrolidone. In this study, we found that fabric softener molecules themselves provide some color care, or DTI. Certain additives to fabric softeners, such as monoalkylquats, greatly enhance the color care of the fabric. DTI treatment in the rinse cycle of the washing sequence makes more sense scientifically and to the consumers, since fabric softeners are designed to coat the textile. Because no competing detergency operations are occurring during the rinse cycle, color care works well in the fabric softener cycle. Addition of organosilicones to fabric softeners reduces wrinkling of fabrics and makes them easier to iron. Softening increases slightly.