Upgrading of lignin-derived bio-oil in non-catalytic plasma reactor: Effects of operating parameters on 4-methylanisole conversion

Abstract

This article investigated an atmospheric pressure dielectric barrier discharge (DBD) plasma reactor to explore the effects of carrier gas type, applied voltage and pulse repetition frequency on upgrading of 4-methylanisole as a lignin-derived bio-oil. A series of experiments were designed to realize the effects of argon (Ar) and hydrogen (H2) on upgrading. The results showed that argon yields higher conversion of 4-methylanisole compared to hydrogen, and both voltage and frequency had positive effects on the conversion of 4-methylanisole. Increasing voltage and frequency led to an increase in the number of active species and subsequently, the number of effective collisions as a result 4-methylanisole conversion and discharge power (DP). In the experiments with applied voltage of 9kV, frequency of 20kHz and existence of Ar as carrier gas, the conversion reached to 29.80% at the DP of 77W. The most abundant products were 4-methyphenol and 2,4-dimethylphenol, which were formed from transalkylation and hydrogenolysis reactions. It was found that the increase in the applied voltage, frequency and Ar percentage of carrier gas (as adjustable parameters), has the same effects on product distribution; since their variation resulted in the same changes in core plasma parameters such as electron energy, temperature and density.