Upgraded β-cyclodextrin-based broad-spectrum adsorbents with enhanced antibacterial property for high-efficient dyeing wastewater remediation

Abstract

The dyeing wastewater contains amounts of refractory organic compounds, and severely endangers the ecosystem and human health. To alleviate this problem, in this study, the low-cost broad-spectrum nano-adsorbent (denoted as CD/CA-g-CS) with strong antibacterial activity has been synthesized by chemical binding of β-cyclodextrin (β-CD) with chitosan (CS) and citric acid (CA) for high-efficient dyes scavenger. Taking advantage of the extraordinary water insolubility, porous nature and abundant surface groups, the synthesized CD/CA-g-CS outperforms the previously reported adsorbents in terms of adsorption performance. The CD/CA-g-CS exhibits ultrahigh adsorption capacities of 801.66, 770.50 and 946.66 mg/g, respectively mg/g for the cationic dyes of malachite green (MG), basic red (BR) and methylene blue (MB), respectively, while 389.64, 619.60 and 429.22 mg/g for the anionic dyes of acid blue (AB), acid red (AR) and acid yellow (AY), respectively. The chemical monolayer absorption is further demonstrated by the analysis based on the pseudo-second-order adsorption kinetics and Langmuir isotherm models. The regenerable CD/CA-g-CS not only performs well in one-step removal of the mixed dyes in the simulated sewage, but also exhibits superior performance in purifying real industrial wastewater. Moreover, CD/CA-g-CS endowed with antibacterial activity leads to an inhibition rate of over 99.99 % for E. coli. The newly developed CD/CA-g-CS adsorbents are highly promising for high-efficient dyeing wastewater remediation.