Upcycling polyamide containing post-consumer Tetra Pak carton packaging to valuable chemicals and recyclable polymer

Abstract

Billion tons of post-consumer Tetra Pak cartons are discarded annually as land and ocean wastes, creating significant environmental problems and resource losses. Recycling of the carton wastes is hindered by its multi-material compositions and low values of the recycled products. In this study, a novel upcycling of the cartons was investigated. A post-consumer carton consisting of paper, polyolefin, and polyamide was directly converted in 210–230 °C tetrahydrofuran containing 10–20 mM acid to produce up to 19.2% of levoglucosenone and 8.6% of furfural by selectively decomposing paper fraction. The remaining solids containing mostly intact polyethylene and polyamide but also a smaller fraction of paper-derived char were separated using a solvent-dissolution method. The xylene-soluble fraction was a recycled polymer similar to the original polyethylene, which was verified by its functional groups, the composition of the pyrolysis products, and the melt rheology results. The xylene-insoluble fraction was a mixture of polyamide and paper-derived char. Upon pyrolysis, caprolactam was produced as the only major vapor product. The remaining, thermally stable paper-derived char could be used as a high-quality solid fuel. Overall, the demonstrated recycling method could potentially maximize the values of the products recovered from carton wastes.