Up-conversion luminescence tuning in Er3+-doped ceramic glass by femtosecond laser pulse at different laser powers**Project supported by the National Natural Science Foundation of China (Grant Nos. 51132004, 11474096, 11604199, U1704145, and 11747101), the Fund from the Science and Technology Commission of Shanghai Municipality, China (Grant No. 14JC1401500), the Henan Provincial Natural Science Foundation, China (Grant No. 182102210117), and the Higher

Abstract

The up-conversion luminescence tuning of rare-earth ions is an important research topic for understanding luminescence mechanisms and promoting related applications. In this paper, we experimentally study the up-conversion luminescence tuning of Er3+-doped ceramic glass excited by the unshaped, V-shaped and cosine-shaped femtosecond laser field with different laser powers. The results show that green and red up-conversion luminescence can be effectively tuned by varying the power or spectral phase of the femtosecond laser field. We further analyze the up-conversion luminescence tuning mechanism by considering different excitation processes, including single-photon absorption (SPA), two-photon absorption (TPA), excited state absorption (ESA), and energy transfer up-conversion (ETU). The relative weight of TPA in the whole excitation process can increase with the increase of the laser power, thereby enhancing the intensity ratio between green and red luminescence (I547/I656). However, the second ETU (ETU2) process can generate red luminescence and reduce the green and red luminescence intensity ratio I547/I656, while the third ESA (ESA3) process can produce green luminescence and enhance its control efficiency. Moreover, the up-conversion luminescence tuning mechanism is further validated by observing the up-conversion luminescence intensity, depending on the laser power and the down-conversion luminescence spectrum under the excitation of 400-nm femtosecond laser pulse. These studies can present a clear physical picture that enables us to understand the up-conversion luminescence tuning mechanism in rare-earth ions, and can also provide an opportunity to tune up-conversion luminescence to promote its related applications.