Unveiling lasing mechanism in CsPbBr3 microsphere cavities.

Abstract

Recently, the light-matter interaction of perovskite microcavities has been widely explored for its great potential in low-threshold lasing devices. However, the mechanism of perovskite lasing remains unclear to date. In this study, we demonstrated high-quality single-mode excitonic lasing in CsPbBr3 microspheres, providing an ideal platform to study the underlying physics of lasing behavior. We show that the lasing mechanism shifts from the exciton-exciton scattering to the exciton-phonon scattering with the increase in temperature from 77 to 300 K, which was verified by temperature-dependent photoluminescence (PL), time-resolved photoluminescence (TRPL) as well as temperature-dependent Raman spectroscopy. Furthermore, by analyzing PL line width broadening with varied temperatures, we found that two different phonon modes were involved in the exciton-phonon scattering process. The scattering from the low-energy phonon (∼8.6 meV) is the dominant source of exciton-phonon coupling in the intermediate temperature range (77 to 230 K), while the high-energy phonon (∼15.3 meV) dominates from 230 K to room temperature. These results confirm the lasing mechanism in such perovskite-based micro/nano-cavities and significantly influence the development of future low-threshold lasers.