Unusually high corrosion resistance in Mo CrNiCo medium entropy alloy enhanced by acidity in aqueous solution

Abstract

• A series of ultra-corrosion-resistant medium entropy alloys were developed. • The corrosion resistance of our alloys unusually increases with acidity in Cl − containing solutions. • The unique anti-corrosion behaviour results from the formation of a protective and compact medium entropy oxide film, which can be attributed to the synergic effect of the chemical complexity on absorption of H 2 O and O 2 . High corrosion resistance of alloys is essential for their structural applications; however, most alloys suffer from degradation of their corrosion resistance with the increasing acidity of their surroundings. Nonetheless, we developed a series of medium-entropy alloys (MEAs) in this work, which exhibit high strength, superior fracture toughness and ultra-high corrosion resistance, outperforming the variety of corrosion resistant alloys hitherto reported. Most interestingly, our MEAs exhibit an unusual anti-corrosion behavior and their corrosion resistance increases with acidity in Cl − containing solutions. Through extensive thermodynamic calculations, density functional theory (DFT) simulations and experiments, we reveal that the unusual anti-corrosion behavior of our MEAs can be attributed to their surface chemical complexity, which facilitates the physio-chemical-absorption of H 2 O and O 2 and thus the rapid formation of metastable medium entropy passive films that contain the lowest amount of defects, as compared to the passive films on conventional alloys reported in the literature.