Abstract
A reaction of vanadyl sulfate VOSO4·3H2O with dimethylmalonic acid strontium salt led to the coordination polymer {Sr(H2O)8[VO(Me2mal)2]}n (1, Me2mal is the dimethylmalonic acid dianion), in which the carboxylate dianions did not form chelate metallocycles with the vanadyl ions. The complex was studied by ESR spectroscopy. The compound 1 exhibited weak spin-spin exchange interactions of ferromagnetic type between the VIV atoms.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR, Division of chemical science
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