Abstract
The results of studies of a basaltic andesite sample complicated by a mineralized crack and voids, with a crack and gas voids filled with secondary mineralization dredged on the Esmeralda underwater volcano, are presented. A detailed comparative study of the mineral composition of the substance lining the crack, the space around the crack, and the part of basaltic andesite unaffected by secondary changes made it possible for the first time for the underwater Esmeralda volcano to establish the presence of an association of minerals that is not characteristic of unaltered volcanic rocks. In the intracrack space and adjacent zones of basaltic andesite, wide ranges of plagioclase composition were determined, isomorphism in the Fe-Ca-pyroxene series was studied, REE oxides, hydroxides and fluorohydroxides were studied, and variability in the composition of minerals in the magnetite-hematite series was shown. It is assumed that tectonic movements led to the emergence of permeable zones in the previously formed basaltic andesites through which new portions of the melt leaked. In a limited space, high fluid gas saturation, temperature and pressure made it possible to extract metal compounds from the melt and host rocks.
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