Abstract

The aniline adduct of dicyclohexyl gallium bromide Cy 2GaBrNH 2Ph ( 1) provides the first example of a structurally characterized dialkyi gallium halide primary amine adduct. X-ray crystallographic data indicate the possibility of an intramolecular hydrogen bond between the bromide and a hydrogen of the amine group (H⋯Br = 2.48 Å).

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