Abstract
AbstractA series of 10,20‐diaryl‐5‐[(E)‐fluoroalkenyl]‐15‐(fluoroalkyl)porphyrins has been synthesized by the reaction of free‐base 5,15‐diarylporphyrins with fluoroalkyl iodides in the presence of Na2S2O4. Subsequent intramolecular cyclization of the corresponding (fluoroalkenyl)porphyrins occurs smoothly in refluxing toluene/H2O. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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