Abstract
In the complex PdL 2 (HL = 4-butylphenyl 2-pyridyl ketone oxime), characterised by spectroscopic techniques and X-ray diffraction analysis, the deprotonated ligand displays a N,O coordination, with the pyridyl nitrogen and the oxime oxygen, which is without precedence in this class of compounds; 1 H NMR spectra, together with structural data on PdL 2, make it possible to distinguish between the N,O and N,N coordination mode in analogous compounds.
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