Untreated municipal solid waste incineration ashes for cement replacement

Abstract

This paper characterised the two different ashes, namely Boiler Ash (BOA) and Residue Ash (RA), collected from Qatar's Municipal Solid Waste Incineration (MSWI) plant through a range of detailed analyses (chemical, physical and morphological). The potential utilisation of these raw MSWI ashes as supplementary cementitious material (SCM) in cement-based composites has been investigated by replacement with 0%, 10%, 20%, and 30% by weight of cement. The effect of the replacement levels on workability, setting time, and strength was investigated. Test results showed that setting time increased and workability decreased with the increase of BOA content. On the contrary, RA substitution decreased the setting time and increased the workability. The highest compressive strength was obtained in RA-incorporated mortars at a 10% replacement ratio. Beyond the 10% replacement ratio, RA incorporation significantly reduced the strength. Due to BOA's high unburned carbon content, BOA substitutions reduced the strength of the mortars. However, the impact of the replacement ratio was not as strong as those in RA mortars. Considering setting time, workability, and compressive strength, BOA and RA's optimum percentage of cement replacement was 20% and 10%, respectively. Heavy metal and salt leaching from MSWI ash-incorporated mortars were evaluated by the monolithic tank test. Results indicated that most toxic metals and salts, except Ba and Cl-, were stabilised in the cement matrix.