Abstract

Poly-Oxymethylene Dimethyl Ethers OMEx are synthetic and potentially-renewable fuels that lead to a notable reduction of the lifecycle CO2 emissions while promoting lower soot emissions than conventional Diesel fuel. In the present contribution, a computational study with a single component OME1 and a multicomponent OMEx fuel has been carried out under reference Spray A conditions from the Engine Combustion Network (ECN), which mimic in-cylinder conditions representative of Diesel engines. For both fuels, three ambient temperature conditions have been swept at constant ambient density. Calculations have been carried out using an Unsteady Flamelet Progress Variable (UFPV) combustion model and detailed chemical mechanisms. For both OMEx-type fuels, low temperature ignition in flamelet configurations start in lean mixtures, which shifts towards the fuel-rich zone and eventually leads to high temperature ignition, similar to typical hydrocarbons. In agreement with corresponding fuel cetane numbers, ignition of OMEx occurs at timings similar to those of n-dodecane, which is the reference fuel for ECN studies, while a delayed ignition is obtained for OME1. However, the actual difference in ignition timing between OMEx and n-dodecane depends on diffusion in the mixture fraction space. Moreover, ignition in spray calculations seems to occur fully on the lean side, especially for OME1, as well as for the low temperature cases. This difference in ignitable mixture range between the canonical flamelet configuration and the spray calculations results from the finite residence time for relevant mixtures in the latter case, compared to an infinite residence time in flamelets. Comparison with experiments show that the modeling approach predicts most combustion metrics for both fuels and temperature values. The combination of ambient temperature and fuel-related reactivity has enabled a transition from a short ignition lifted diffusion flame structure (OMEx at 1000–900 K) towards long ignition cases, where lift-off length may eventually be longer than the maximum length of the stoichiometric surface. This results in a reaction front stabilization at very lean conditions, i.e. a type of lean mixing-controlled flame.

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